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4-Chlorophenylboronic acid

CAS No.
1679-18-1
Chemical Name:
4-Chlorophenylboronic acid
Synonyms
4-CHLOROBENZENEBORONIC ACID;AC 34441;NSC 25408;WLN: QBQR DG;AKOS BRN-0011;RARECHEM AH PB 0178;orobenzeneboronic Acid;p-chlorophenylboronic aci;4-Chlorophenylbronic Acid;The effects of boric acid
CBNumber:
CB0307561
Molecular Formula:
C6H6BClO2
Molecular Weight:
156.37
MDL Number:
MFCD00039137
MOL File:
1679-18-1.mol
MSDS File:
SDS
Modify Date:2023-03-28 11:43:54

4-Chlorophenylboronic acid Properties

Melting point 284-289 °C(lit.)
Boiling point 295.4±42.0 °C(Predicted)
Density 1.32±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility DMSO
pka 8.39±0.10(Predicted)
form Crystalline Powder
color Off-white to beige
Water Solubility 2.5 g/100 mL
BRN 2936346
InChI InChI=1S/C6H6BClO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
InChIKey CAYQIZIAYYNFCS-UHFFFAOYSA-N
SMILES B(C1=CC=C(Cl)C=C1)(O)O
CAS DataBase Reference 1679-18-1(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII AB2T8N4T4C

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P301+P312+P330
Hazard Codes  Xn,Xi
Risk Statements  20/21/22-36/37/38
Safety Statements  36-37/39-26
WGK Germany  3
RTECS  CY8950000
TSCA  No
HazardClass  IRRITANT
HS Code  29319090
NFPA 704
0
2 0

4-Chlorophenylboronic acid price More Price(50)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 417548 4-Chlorophenylboronic acid 95% 1679-18-1 1g $35 2023-01-07 Buy
Sigma-Aldrich 417548 4-Chlorophenylboronic acid 95% 1679-18-1 10g $114 2023-01-07 Buy
TCI Chemical C1473 4-Chlorophenylboronic Acid (contains varying amounts of Anhydride) 1679-18-1 5g $47 2023-01-07 Buy
TCI Chemical C1473 4-Chlorophenylboronic Acid (contains varying amounts of Anhydride) 1679-18-1 25g $136 2023-01-07 Buy
Alfa Aesar A15657 4-Chlorobenzeneboronic acid, 98+% 1679-18-1 1g $20.16 2023-01-06 Buy
Product number Packaging Price Buy
417548 1g $35 Buy
417548 10g $114 Buy
C1473 5g $47 Buy
C1473 25g $136 Buy
A15657 1g $20.16 Buy

4-Chlorophenylboronic acid Chemical Properties,Uses,Production

Chemical Properties

off-white to beige crystalline powder

Uses

suzuki reaction

Uses

4-Chlorobenzeneboronic Acid is used as a catalyst for the preparation of 4-hydroxycoumarin derivatives which display antitrypanosomal and antioxidant properties. It is also used as a catalyst for the asymmetric borane reduction of electron-deficient ketones.

Uses

4-Chlorophenylboronic acid can be used as a reactant in:

  • Palladium-catalyzed direct arylation.
  • Cyclopalladation.
  • Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation.
  • Copper-mediated ligandless aerobic fluoroalkylation.
  • Pd-catalyzed arylative cyclization.
  • Ruthenium catalyzed direct arylation.
  • Ligand-free copper-catalyzed coupling reactions.
  • Regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions.

It can also be used to prepare:
  • Substituted diarylmethylidenefluorenes via Suzuki coupling reaction.
  • Baclofen lactam by Suzuki coupling of a pyrrolinyl tosylate, followed by hydrogenation reaction.
  • Palladium(II) thiocarboxamide complexes as Suzuki coupling catalysts.
  • Biaryls by Suzuki reactions of aryl chlorides, bromides, and iodides with arylboronic acids.

106-47-8
1679-18-1
Synthesis of 4-Chlorophenylboronic acid from 4-Chloroaniline

4-Chlorophenylboronic acid Suppliers

Global( 643)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Maison Chemical Co.,Ltd.
+86-85381176 +86-008615511852758 ruby@maisonchem.com.cn China 445 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52877 58
ZHEJIANG ESTCHEM CO.,LTD
15957180504 sales@zjestchem.com China 193 58
Springchem New Material Technology Co.,Limited
+86-021-62885108 +8613917661608 info@spring-chem.com China 2068 57
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29810 60
Henan DaKen Chemical CO.,LTD.
+86-371-66670886 info@dakenchem.com China 17713 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21975 55
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070 product@chemlin.com.cn CHINA 3012 60
ATK CHEMICAL COMPANY LIMITED
21-51619050 ivan@atkchemical.com China 31382 60
Zjartschem
+86-571-8723 8903 jocelynpan@zjarts.com jocelynpan@zjarts.com CHINA 993 58

View Lastest Price from 4-Chlorophenylboronic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Chlorophenylboronic acid pictures 2023-02-09 4-Chlorophenylboronic acid
1679-18-1
US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
4-Chlorophenylboronic acid pictures 2022-12-23 4-Chlorophenylboronic acid
1679-18-1
US $171.80 / KG 1g 99% 10Tons Baoji Guokang Bio-Technology Co., Ltd.
4-Chlorophenylboronic acid pictures 2022-10-15 4-Chlorophenylboronic acid
1679-18-1
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.

4-Chlorophenylboronic acid Spectrum

4-Chlorophenylboronic acid,97% 4-Chlorophenylboronic acid, May contain varying amounts of anhydride, 97% 4-Chlorophenylboronic acid,4-Chlorobenzeneboronic acid p-chlorophenylboronic aci (4-chlorophenyl)boronic acid(SALTDATA: 0.7H2O) 4-Chlorophenylboronic acid, 97% 5GR NSC 25408 BORONIC ACID, (4-CHLOROPHENYL)-;P-CHLOROBENZENEBORONIC ACID; p-chloro-benzeneboronicaci (p-chlorophenyl)metaboric acid 4-Chlorophenylboronicacid,min.97% 4-CHLOROBENZENEBORONIC ACID / 4-CHLOROPHENYLBORONIC ACID PARACHLOROPHENYLBORONIC ACID 4-Chlorophenylboronic acid ,98% 4-Chlorophenylboronic acid, min. 97% (4-Chlorophenyl)boranic acid 4-Chlorophenylboranic acid 4-Chlorophenylboron dihydoxide 4-Chlorobenzeneboronic acid, 98+% 4-Chlorophenylboronic Acid (contains varying amounts of Anhydride) orobenzeneboronic Acid 4-Chlorophenylbronic Acid The effects of boric acid 4-Chlorophenylboronic acid 95% AC 34441 Benzeneboronic acid, p-chloro- WLN: QBQR DG B-(4-Chlorophenyl)boronic acid BORONIC ACID, (4-CHLOROPHENYL)- AKOS BRN-0011 4-CHLOROPHENYLBORNIC ACID 4-CHLOROPHENYLBORONIC ACID 4-CHLOROBENZENEBORONIC ACID P-CHLOROPHENYLBORONIC ACID P-CHLORO BENZENE BORONIC ACID RARECHEM AH PB 0178 boronicacid,p-chlorophenyl 4-Chlorophenylboronic acid,99% Boronic acid, B-(4-chlorophenyl)- 4-Chlorophenylboronic Acid extrapure, 97% 4-Chlorophenylboornic acid 4-Chlorophenylboronic acid supplier in China CAS NO.1679-18-1 CAS NO.1679-18-1 13C6]-4-Chlorobenzeneboronic acid 1679-18-1 1679-81-1 B (Classes of Boron Compounds) Boronic Acids Organometallic Reagents Boronic Acids and Derivatives Aryl blocks BoronicAcids Boronic Acid series Fluorin-contained phenyl boronic acid series Heterocyclic Compounds Boronic Acid Aryl Organoborons